Some Experimental and Theoretical Studies of Molecular Interactions Prevailing in Cyclic Diether + 1-alkanols Binary Liquid Mixtures Through Ultrasonic Measurements

Dhirendra Kumar Sharma; Suneel Kumar; Chandra Pal Prajapati; Sandeep Sahu

doi:doi:10.11648/j.ajac.20251306.12

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Some Experimental and Theoretical Studies of Molecular Interactions Prevailing in Cyclic Diether + 1-alkanols Binary Liquid Mixtures Through Ultrasonic Measurements

Dhirendra Kumar Sharma^*

, Suneel Kumar

, Chandra Pal Prajapati

, Sandeep Sahu

Published in American Journal of Applied Chemistry (Volume 13, Issue 6)

Received: 19 November 2025 Accepted: 4 December 2025 Published: 29 December 2025

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Abstract

The density, viscosity and sound velocity for binary mixtures of 1,3-dioxolane + pentanol, 1,3-dioxolane + hexanol, 1,3-dioxolane + heptanol, 1,3-dioxolane + octanol, 1,3-dioxolane + nonanol and 1,3-dioxolane + decanol have been measured at the temperature 298.15 K, are conducted at atmospheric pressure. From these experimental values, various thermodynamic and excess thermodynamic properties were calculated. The adiabatic compressibility (β_ad), excess adiabatic compressibility (β_ad^E), inter molecular free length (L_f), excess inter molecular free length (L_f^E), enthalpy (H), excess enthalpy (H^E), free volume (V_f), excess free volume (V_f^E)), internal pressure (P_i), excess internal pressure (p_i^E) have been in vestigated from density (ρ), viscosity (η) and sound velocity (u) measurements of six binary liquid mixtures of 1,3-Dioxolane with pentanol, hexanol, heptanol, octanol, nonanol and decanol over the entire composition range of mole fractions at 298.15K. An excess values of adiabatic compressibility (β_ad^E), inter molecular free length (L_f^E)), excess enthalpy (H^E), excess free volume (L_f^E) and excess internal pressure (p_i^E) were plotted against the mole fraction of 1,3-dioxolane over the whole composition range. The excess properties are found to be negative depending on the molecular interactions and the nature of the liquid mixtures. The systems studied exhibit very strong cross association through hydrogen bonding.

Published in	American Journal of Applied Chemistry (Volume 13, Issue 6)
DOI	10.11648/j.ajac.20251306.12
Page(s)	164-179
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2025. Published by Science Publishing Group

Keywords

Binary Mixtures, Adiabatic Compressibility, Enthalpy, Free Volume, Internal Pressure, Hydrogen Bonding, Molecular Interaction

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APA Style

Sharma, D. K., Kumar, S., Prajapati, C. P., Sahu, S. (2025). Some Experimental and Theoretical Studies of Molecular Interactions Prevailing in Cyclic Diether + 1-alkanols Binary Liquid Mixtures Through Ultrasonic Measurements. American Journal of Applied Chemistry, 13(6), 164-179. https://doi.org/10.11648/j.ajac.20251306.12

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ACS Style

Sharma, D. K.; Kumar, S.; Prajapati, C. P.; Sahu, S. Some Experimental and Theoretical Studies of Molecular Interactions Prevailing in Cyclic Diether + 1-alkanols Binary Liquid Mixtures Through Ultrasonic Measurements. Am. J. Appl. Chem. 2025, 13(6), 164-179. doi: 10.11648/j.ajac.20251306.12

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AMA Style

Sharma DK, Kumar S, Prajapati CP, Sahu S. Some Experimental and Theoretical Studies of Molecular Interactions Prevailing in Cyclic Diether + 1-alkanols Binary Liquid Mixtures Through Ultrasonic Measurements. Am J Appl Chem. 2025;13(6):164-179. doi: 10.11648/j.ajac.20251306.12

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@article{10.11648/j.ajac.20251306.12,
  author = {Dhirendra Kumar Sharma and Suneel Kumar and Chandra Pal Prajapati and Sandeep Sahu},
  title = {Some Experimental and Theoretical Studies of Molecular Interactions Prevailing in Cyclic Diether + 1-alkanols Binary Liquid Mixtures Through Ultrasonic Measurements},
  journal = {American Journal of Applied Chemistry},
  volume = {13},
  number = {6},
  pages = {164-179},
  doi = {10.11648/j.ajac.20251306.12},
  url = {https://doi.org/10.11648/j.ajac.20251306.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20251306.12},
  abstract = {The density, viscosity and sound velocity for binary mixtures of 1,3-dioxolane + pentanol, 1,3-dioxolane + hexanol, 1,3-dioxolane + heptanol, 1,3-dioxolane + octanol, 1,3-dioxolane + nonanol and 1,3-dioxolane + decanol have been measured at the temperature 298.15 K, are conducted at atmospheric pressure. From these experimental values, various thermodynamic and excess thermodynamic properties were calculated. The adiabatic compressibility (βad), excess adiabatic compressibility (βadE), inter molecular free length (Lf), excess inter molecular free length (LfE), enthalpy (H), excess enthalpy (HE), free volume (Vf), excess free volume (VfE)), internal pressure (Pi), excess internal pressure (piE) have been in vestigated from density (ρ), viscosity (η) and sound velocity (u) measurements of six binary liquid mixtures of 1,3-Dioxolane with pentanol, hexanol, heptanol, octanol, nonanol and decanol over the entire composition range of mole fractions at 298.15K. An excess values of adiabatic compressibility (βadE), inter molecular free length (LfE)), excess enthalpy (HE), excess free volume (LfE) and excess internal pressure (piE) were plotted against the mole fraction of 1,3-dioxolane over the whole composition range. The excess properties are found to be negative depending on the molecular interactions and the nature of the liquid mixtures. The systems studied exhibit very strong cross association through hydrogen bonding.},
 year = {2025}
}

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TY  - JOUR
T1  - Some Experimental and Theoretical Studies of Molecular Interactions Prevailing in Cyclic Diether + 1-alkanols Binary Liquid Mixtures Through Ultrasonic Measurements
AU  - Dhirendra Kumar Sharma
AU  - Suneel Kumar
AU  - Chandra Pal Prajapati
AU  - Sandeep Sahu
Y1  - 2025/12/29
PY  - 2025
N1  - https://doi.org/10.11648/j.ajac.20251306.12
DO  - 10.11648/j.ajac.20251306.12
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 164
EP  - 179
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20251306.12
AB  - The density, viscosity and sound velocity for binary mixtures of 1,3-dioxolane + pentanol, 1,3-dioxolane + hexanol, 1,3-dioxolane + heptanol, 1,3-dioxolane + octanol, 1,3-dioxolane + nonanol and 1,3-dioxolane + decanol have been measured at the temperature 298.15 K, are conducted at atmospheric pressure. From these experimental values, various thermodynamic and excess thermodynamic properties were calculated. The adiabatic compressibility (βad), excess adiabatic compressibility (βadE), inter molecular free length (Lf), excess inter molecular free length (LfE), enthalpy (H), excess enthalpy (HE), free volume (Vf), excess free volume (VfE)), internal pressure (Pi), excess internal pressure (piE) have been in vestigated from density (ρ), viscosity (η) and sound velocity (u) measurements of six binary liquid mixtures of 1,3-Dioxolane with pentanol, hexanol, heptanol, octanol, nonanol and decanol over the entire composition range of mole fractions at 298.15K. An excess values of adiabatic compressibility (βadE), inter molecular free length (LfE)), excess enthalpy (HE), excess free volume (LfE) and excess internal pressure (piE) were plotted against the mole fraction of 1,3-dioxolane over the whole composition range. The excess properties are found to be negative depending on the molecular interactions and the nature of the liquid mixtures. The systems studied exhibit very strong cross association through hydrogen bonding.
VL  - 13
IS  - 6
ER  -

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Author Information

Dhirendra Kumar Sharma

Department of Chemistry, Bundelkhand University, Jhansi (U.P), India

Contact Email

http://orcid.org/0000-0002-4171-8372
Suneel Kumar

Department of Chemistry, Bundelkhand University, Jhansi (U.P), India

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http://orcid.org/0000-0001-6936-349X
Chandra Pal Prajapati

Department of Chemistry, Bundelkhand University, Jhansi (U.P), India

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http://orcid.org/0000-0002-6343-4063
Sandeep Sahu

Department of Chemistry, Bundelkhand University, Jhansi (U.P), India

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http://orcid.org/0009-0008-4882-1808

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APA Style

Sharma, D. K., Kumar, S., Prajapati, C. P., Sahu, S. (2025). Some Experimental and Theoretical Studies of Molecular Interactions Prevailing in Cyclic Diether + 1-alkanols Binary Liquid Mixtures Through Ultrasonic Measurements. American Journal of Applied Chemistry, 13(6), 164-179. https://doi.org/10.11648/j.ajac.20251306.12

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ACS Style

Sharma, D. K.; Kumar, S.; Prajapati, C. P.; Sahu, S. Some Experimental and Theoretical Studies of Molecular Interactions Prevailing in Cyclic Diether + 1-alkanols Binary Liquid Mixtures Through Ultrasonic Measurements. Am. J. Appl. Chem. 2025, 13(6), 164-179. doi: 10.11648/j.ajac.20251306.12

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AMA Style

Sharma DK, Kumar S, Prajapati CP, Sahu S. Some Experimental and Theoretical Studies of Molecular Interactions Prevailing in Cyclic Diether + 1-alkanols Binary Liquid Mixtures Through Ultrasonic Measurements. Am J Appl Chem. 2025;13(6):164-179. doi: 10.11648/j.ajac.20251306.12

Copy | Download

@article{10.11648/j.ajac.20251306.12,
  author = {Dhirendra Kumar Sharma and Suneel Kumar and Chandra Pal Prajapati and Sandeep Sahu},
  title = {Some Experimental and Theoretical Studies of Molecular Interactions Prevailing in Cyclic Diether + 1-alkanols Binary Liquid Mixtures Through Ultrasonic Measurements},
  journal = {American Journal of Applied Chemistry},
  volume = {13},
  number = {6},
  pages = {164-179},
  doi = {10.11648/j.ajac.20251306.12},
  url = {https://doi.org/10.11648/j.ajac.20251306.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20251306.12},
  abstract = {The density, viscosity and sound velocity for binary mixtures of 1,3-dioxolane + pentanol, 1,3-dioxolane + hexanol, 1,3-dioxolane + heptanol, 1,3-dioxolane + octanol, 1,3-dioxolane + nonanol and 1,3-dioxolane + decanol have been measured at the temperature 298.15 K, are conducted at atmospheric pressure. From these experimental values, various thermodynamic and excess thermodynamic properties were calculated. The adiabatic compressibility (βad), excess adiabatic compressibility (βadE), inter molecular free length (Lf), excess inter molecular free length (LfE), enthalpy (H), excess enthalpy (HE), free volume (Vf), excess free volume (VfE)), internal pressure (Pi), excess internal pressure (piE) have been in vestigated from density (ρ), viscosity (η) and sound velocity (u) measurements of six binary liquid mixtures of 1,3-Dioxolane with pentanol, hexanol, heptanol, octanol, nonanol and decanol over the entire composition range of mole fractions at 298.15K. An excess values of adiabatic compressibility (βadE), inter molecular free length (LfE)), excess enthalpy (HE), excess free volume (LfE) and excess internal pressure (piE) were plotted against the mole fraction of 1,3-dioxolane over the whole composition range. The excess properties are found to be negative depending on the molecular interactions and the nature of the liquid mixtures. The systems studied exhibit very strong cross association through hydrogen bonding.},
 year = {2025}
}

Copy | Download

TY  - JOUR
T1  - Some Experimental and Theoretical Studies of Molecular Interactions Prevailing in Cyclic Diether + 1-alkanols Binary Liquid Mixtures Through Ultrasonic Measurements
AU  - Dhirendra Kumar Sharma
AU  - Suneel Kumar
AU  - Chandra Pal Prajapati
AU  - Sandeep Sahu
Y1  - 2025/12/29
PY  - 2025
N1  - https://doi.org/10.11648/j.ajac.20251306.12
DO  - 10.11648/j.ajac.20251306.12
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 164
EP  - 179
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20251306.12
AB  - The density, viscosity and sound velocity for binary mixtures of 1,3-dioxolane + pentanol, 1,3-dioxolane + hexanol, 1,3-dioxolane + heptanol, 1,3-dioxolane + octanol, 1,3-dioxolane + nonanol and 1,3-dioxolane + decanol have been measured at the temperature 298.15 K, are conducted at atmospheric pressure. From these experimental values, various thermodynamic and excess thermodynamic properties were calculated. The adiabatic compressibility (βad), excess adiabatic compressibility (βadE), inter molecular free length (Lf), excess inter molecular free length (LfE), enthalpy (H), excess enthalpy (HE), free volume (Vf), excess free volume (VfE)), internal pressure (Pi), excess internal pressure (piE) have been in vestigated from density (ρ), viscosity (η) and sound velocity (u) measurements of six binary liquid mixtures of 1,3-Dioxolane with pentanol, hexanol, heptanol, octanol, nonanol and decanol over the entire composition range of mole fractions at 298.15K. An excess values of adiabatic compressibility (βadE), inter molecular free length (LfE)), excess enthalpy (HE), excess free volume (LfE) and excess internal pressure (piE) were plotted against the mole fraction of 1,3-dioxolane over the whole composition range. The excess properties are found to be negative depending on the molecular interactions and the nature of the liquid mixtures. The systems studied exhibit very strong cross association through hydrogen bonding.
VL  - 13
IS  - 6
ER  -

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