Abattoir wastewater (AWW) contains a high level of organic pollutants due to the presence of toxic contaminants such as blood, feces from animals, and detergents from cleaning activities. In this study, the wastewater from the slaughterhouse was treated with a cobalt-catalyzed persulfate oxidation reaction to determine how well persulfate works as an oxidant to get rid of and break down organic materials. The water tested had a high organic load (COD = 2100mg/L), a pH of 7.7, and a BOD of 800mg/L. Time (10–90min), temperature (25–75°C), acid content (0.5–2.5M), persulfate (0.025–0.1g), and cobalt catalyst (50–150 mg/L) were all evaluated as operational conditions. Temperature and acid content was found to have a positive effect on COD elimination while increasing the residence time. The reaction conditions were optimized at a constant dose of 0.3 g of potassium persulfate, 1 M acid concentration in 30 minutes, and a maximum temperature of 60°C. At optimum conditions, approximately 98.46% of the COD was removed. The COD elimination rate was 92.85% at a low amount of potassium persulfate (0.075g). The study concludes that the developed approach could be used to efficiently treat abattoir wastewater.
| Published in | American Journal of Chemical Engineering (Volume 12, Issue 1) |
| DOI | 10.11648/j.ajche.20241201.12 |
| Page(s) | 6-12 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Chemical Oxidation, Abattoir Treatment, COD, Wastewater, Cobalt
| [1] | Alfonso-Muniozguren, P., Hazzwan Bohari, M., Sicilia, A., Avignone-Rossa, C., Bussemaker, M., Saroj, D., & Lee, J. (2020). Tertiary treatment of real abattoir wastewater using combined acoustic cavitation and ozonation. Ultrasonics Sonochemistry, 64. https://doi.org/10.1016/j.ultsonch.2020.104986 |
| [2] | Akinola, J. O., Olawusi-Peters, O. O., & Apkambang, V. O. E. (2020). Human health risk assessment of TPHs in brackish water prawn (Nematopalaemon hastatus, AURIVILLUS, 1898). Heliyon, 6(1). https://doi.org/10.1016/j.heliyon.2020.e03234 |
| [3] | Akinola, J. O., Olawusi-Peters, O. O., & Akpambang, V. O. E. (2019). Ecological hazards of Total petroleum hydrocarbon in brackish water white Shrimp Nematopalaemon hastatus (AURIVILLUS 1898). Egyptian Journal of Aquatic Research, 45(3). https://doi.org/10.1016/j.ejar.2019.07.004 |
| [4] | Ogungbile, P., Ajibare, A. O., Ayeku, P., & Akinola, J. (2021). Bio-Tolerance Potential and Environmental Risks Assessment of Oreochromis Niloticus and Lpomoea Aquatica in Agodi Reservoir, Nigeria. In ResearchSquare. https://doi.org/10.21203/rs.3.rs-763032 |
| [5] | Philipp, M., Jabri, K. M., Wellmann, J., Akrout, H., Bousselmi, L., & Geißen, S. U. (2021). Slaughterhouse wastewater treatment: A review on recycling and reuse possibilities. In Water (Switzerland) (Vol. 13, Issue 22). https://doi.org/10.3390/w13223175 |
| [6] | Feng, H., Hu, L., Mahmood, Q., Fang, C., Qiu, C., & Shen, D. (2009). Effects of temperature and feed strength on a carrier anaerobic baffled reactor treating dilute wastewater. Desalination, 239(1–3). https://doi.org/10.1016/j.desal.2008.03.011 |
| [7] | OECD/FAO (2022), OECD-FAO Agricultural Outlook 2022-2031, OECD Publishing, Paris, https://doi.org/10.1787/f1b0b29c-en |
| [8] | Hoekstra, A. Y., & Chapagain, A. K. (2007). Water footprints of nations: Water use by people as a function of their consumption pattern. Water Resources Management, 21(1). https://doi.org/10.1007/s11269-006-9039-x |
| [9] | Hoekstra, A. Y., & Mekonnen, M. M. (2012). The water footprint of humanity. Proceedings of the National Academy of Sciences of the United States of America, 109(9). https://doi.org/10.1073/pnas.1109936109 |
| [10] | Bustillo-Lecompte, C. F., & Mehrvar, M. (2015). Slaughterhouse wastewater characteristics, treatment, and management in the meat processing industry: A review on trends and advances. In Journal of Environmental Management (Vol. 161). https://doi.org/10.1016/j.jenvman.2015.07.008 |
| [11] | Mulu, A., & Ayenew, T. (2015). Characterization of Abattoir Wastewater and Evaluation of the Effectiveness of the Wastewater Treatment Systems in Luna and Kera Abattoirs in Central Ethiopia. International Journal of Scientific & Engineering Research, 6(4). |
| [12] | Olusola-Makinde, O. O., Arotupin, D. J., & Okoh, A. I. (2022). Optimization of hemolysin formation in Alcaligenes species isolated from abattoir wastewater samples in Akure, Ondo State, Nigeria. Kuwait Journal of Science, 49(3). https://doi.org/10.48129/kjs.9406 |
| [13] | European IPPC Bureau. Reference Document on Best Available Techniques in the Slaughterhouses and Animal By-Products Industries; European IPPC Bureau: Seville, Spain, 2005. Available online: https://eippcb.jrc.ec.europa.eu/sites/default/files/2020-01/sa_bref_0505.pdf |
| [14] | Compton, M., Willis, S., Rezaie, B., & Humes, K. (2018). Food processing industry energy and water consumption in the Pacific northwest. In Innovative Food Science and Emerging Technologies (Vol. 47). https://doi.org/10.1016/j.ifset.2018.04.001 |
| [15] | World Water Development. The United Nations World Water Development Report 2018—Nature-Based Solutions for Water; UNESCO Publishing: Paris, France, 2018. |
| [16] | Valta, K., Kosanovic, T., Malamis, D., Moustakas, K., & Loizidou, M. (2015). Overview of water usage and wastewater management in the food and beverage industry. Desalination and Water Treatment, 53(12). https://doi.org/10.1080/19443994.2014.934100 |
| [17] | Nkeshita, F. C., Adekunle, A. A., Onaneye, R. B., & Yusuf, O. (2020). Removal of pollutants from abattoir wastewater using a pilot-scale bamboo constructed wetland system. Environmental Engineering, 7(2). https://doi.org/10.37023/ee.7.2.4 |
| [18] | Olanrewaju, O. O and Adewumi, J. R. (2011). Treatment of abattoir wastewater using septic and multimedia anaerobic filtration tanks from a slaughterhouse in Akure, Southwest Nigeria. African Journal of Science, Technology, and Innovation Development, 3(4): 12-34. |
| [19] | Liu, Y., & Tay, J. H. (2004). State of the art of biogranulation technology for wastewater treatment. Biotechnology Advances, 22(7). https://doi.org/10.1016/j.biotechadv.2004.05.001 |
| [20] | United States Environmental Protection Agency (USEPA). (2004). Effluent limitations guidelines and new source performance standards for the meat and poultry products point source category. |
| [21] | Chukwu, O., Adeoye, P. A., & Chidiebere, I. (2011). Abattoir wastes generation, management and the environment: a case of Minna, North Central Nigeria. International Journal of Biosciences, 1(6). |
| [22] | Okey-Onyesolu, C. F., Chukwuma, E. C., Okoye, C. C., & Onukwuli, O. D. (2020). Response Surface Methodology optimization of chito-protein synthesized from crab shell in treatment of abattoir wastewater. Heliyon, 6(10). https://doi.org/10.1016/j.heliyon.2020.e05186 |
| [23] | Okey-Onyesolu, C. F., Chukwuma, E. C., Okoye, C. C., & Taiwo, A. E. (2022). Application of synthesized Fish Scale Chito-Protein (FSC) for the treatment of abattoir wastewater: Coagulation-flocculation kinetics and equilibrium modeling. Scientific African, 17. https://doi.org/10.1016/j.sciaf.2022.e01367 |
| [24] | Arvanitoyannis, I. S., & Ladas, D. (2008). Meat waste treatment methods and potential uses. International Journal of Food Science and Technology, 43(3). https://doi.org/10.1111/j.1365-2621.2006.01492.x |
| [25] | Asselin, M., Drogui, P., Benmoussa, H., & Blais, J. F. (2008). Effectiveness of electrocoagulation process in removing organic compounds from slaughterhouse wastewater using monopolar and bipolar electrolytic cells. Chemosphere, 72(11). https://doi.org/10.1016/j.chemosphere.2008.04.067 |
| [26] | Harif, T., Khai, M., & Adin, A. (2012). Electrocoagulation versus chemical coagulation: Coagulation/flocculation mechanisms and resulting floc characteristics. Water Research, 46(10). https://doi.org/10.1016/j.watres.2012.03.034 |
| [27] | Ozturk, D., Yilmaz, A. E., & Sapci Ayas, Z. (2021). Electrochemical mineralization of abattoir wastewater with continuous system. International Journal of Environmental Science and Technology, 18(12). https://doi.org/10.1007/s13762-020-03109-w |
| [28] | Mohajerani, M., Mehrvar, M., & Ein-Mozaffari, F. (2009). An overview of the integration of advanced oxidation technologies and other processes for water and wastewater treatment. Int J Eng, 3(2). |
| [29] | Baker, B. R., Mohamed, R., Al-Gheethi, A., & Aziz, H. A. (2021). Advanced technologies for poultry slaughterhouse wastewater treatment: A systematic review. Journal of Dispersion Science and Technology, 42(6). https://doi.org/10.1080/01932691.2020.1721007 |
| [30] | APHA, W. E. F. (1998). AWWA, 1995. Standard Methods for the Examination of Water and Wastewater. Amer. Pub. Health Association. Washington DC. |
| [31] | APHA. (2005). Standard Methods for the Examination of Water and Wastewater. Standard Methods. https://doi.org/ISBN 9780875532356 |
| [32] | APHA, AWWA, WEF. (2012). Standard Methods for Examination of Water and Wastewater. Washington: American Public Health Association. |
| [33] | Friedrich, G., Chapman, D., & Beim, A. (1996). The Use of Biological Material in Water Quality Assessments: A Guide to the Use of Biota, Sediments and Water in Environmental Monitoring. In Quality. |
| [34] | WHO. (2004). World Health Organisation: Guidelines for drinking water quality, Third Edition, Vol. 1. Recommendations. Environmental Pollution Series A, Ecological and Biological, 1. |
| [35] | Adewumi, J. R., Babatola, J. O., and Adejuwon, E. O., (2016): Assessment of Abattoir Wastes Management Strategy in Akure South-West Nigeria. FUTO Journal Series. 2(1): 186-194. |
| [36] | Adebayo, A. O., Ajiboye, E. A. and Ewetumo T. (2015). Removal of organic pollutants from abattoir wastewater using electro-coagulation. FUTA Journal of Research in Sciences. (1): 15-24. |
| [37] | Peña, M., Coca, M., González, G., Rioja, R., & García, M. T. (2003). Chemical oxidation of wastewater from molasses fermentation with ozone. Chemosphere, 51(9). https://doi.org/10.1016/S0045-6535(03)00159-0 |
| [38] | Türgay, O., Ersöz, G., Atalay, S., Forss, J., & Welander, U. (2011). The treatment of azo dyes found in textile industry wastewater by anaerobic biological method and chemical oxidation. Separation and Purification Technology, 79(1). https://doi.org/10.1016/j.seppur.2011.03.007 |
| [39] | Olawusi-Peters, O. O. and Akinola, J. O. (2018). Physico-Chemical Parameters and Microbial Load in Water, Sediment and Organisms (Nematopalaemon Hastatus and Farfantepenaeus Notialis) in Ondo State, Nigeria. Applied Tropical Agriculture. 24(1): 37-46. |
APA Style
Olawumi, A. R., Ojo, A. A., Dikeagu, A. C., Oluwatobi, A. J. (2024). Oxidation of Abattoir Wastewater Using Cobalt-Catalyzed Potassium Persulfate. American Journal of Chemical Engineering, 12(1), 6-12. https://doi.org/10.11648/j.ajche.20241201.12
ACS Style
Olawumi, A. R.; Ojo, A. A.; Dikeagu, A. C.; Oluwatobi, A. J. Oxidation of Abattoir Wastewater Using Cobalt-Catalyzed Potassium Persulfate. Am. J. Chem. Eng. 2024, 12(1), 6-12. doi: 10.11648/j.ajche.20241201.12
AMA Style
Olawumi AR, Ojo AA, Dikeagu AC, Oluwatobi AJ. Oxidation of Abattoir Wastewater Using Cobalt-Catalyzed Potassium Persulfate. Am J Chem Eng. 2024;12(1):6-12. doi: 10.11648/j.ajche.20241201.12
Share This Article
Twitter
Linked In
Facebook
Copy
Download@article{10.11648/j.ajche.20241201.12,
author = {Ayoola Rebecca Olawumi and Adebayo Albert Ojo and Ahuchaogu Chinedu Dikeagu and Akinola Joshua Oluwatobi},
title = {Oxidation of Abattoir Wastewater Using Cobalt-Catalyzed Potassium Persulfate},
journal = {American Journal of Chemical Engineering},
volume = {12},
number = {1},
pages = {6-12},
doi = {10.11648/j.ajche.20241201.12},
url = {https://doi.org/10.11648/j.ajche.20241201.12},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20241201.12},
abstract = {Abattoir wastewater (AWW) contains a high level of organic pollutants due to the presence of toxic contaminants such as blood, feces from animals, and detergents from cleaning activities. In this study, the wastewater from the slaughterhouse was treated with a cobalt-catalyzed persulfate oxidation reaction to determine how well persulfate works as an oxidant to get rid of and break down organic materials. The water tested had a high organic load (COD = 2100mg/L), a pH of 7.7, and a BOD of 800mg/L. Time (10–90min), temperature (25–75°C), acid content (0.5–2.5M), persulfate (0.025–0.1g), and cobalt catalyst (50–150 mg/L) were all evaluated as operational conditions. Temperature and acid content was found to have a positive effect on COD elimination while increasing the residence time. The reaction conditions were optimized at a constant dose of 0.3 g of potassium persulfate, 1 M acid concentration in 30 minutes, and a maximum temperature of 60°C. At optimum conditions, approximately 98.46% of the COD was removed. The COD elimination rate was 92.85% at a low amount of potassium persulfate (0.075g). The study concludes that the developed approach could be used to efficiently treat abattoir wastewater.
},
year = {2024}
}
TY - JOUR T1 - Oxidation of Abattoir Wastewater Using Cobalt-Catalyzed Potassium Persulfate AU - Ayoola Rebecca Olawumi AU - Adebayo Albert Ojo AU - Ahuchaogu Chinedu Dikeagu AU - Akinola Joshua Oluwatobi Y1 - 2024/03/13 PY - 2024 N1 - https://doi.org/10.11648/j.ajche.20241201.12 DO - 10.11648/j.ajche.20241201.12 T2 - American Journal of Chemical Engineering JF - American Journal of Chemical Engineering JO - American Journal of Chemical Engineering SP - 6 EP - 12 PB - Science Publishing Group SN - 2330-8613 UR - https://doi.org/10.11648/j.ajche.20241201.12 AB - Abattoir wastewater (AWW) contains a high level of organic pollutants due to the presence of toxic contaminants such as blood, feces from animals, and detergents from cleaning activities. In this study, the wastewater from the slaughterhouse was treated with a cobalt-catalyzed persulfate oxidation reaction to determine how well persulfate works as an oxidant to get rid of and break down organic materials. The water tested had a high organic load (COD = 2100mg/L), a pH of 7.7, and a BOD of 800mg/L. Time (10–90min), temperature (25–75°C), acid content (0.5–2.5M), persulfate (0.025–0.1g), and cobalt catalyst (50–150 mg/L) were all evaluated as operational conditions. Temperature and acid content was found to have a positive effect on COD elimination while increasing the residence time. The reaction conditions were optimized at a constant dose of 0.3 g of potassium persulfate, 1 M acid concentration in 30 minutes, and a maximum temperature of 60°C. At optimum conditions, approximately 98.46% of the COD was removed. The COD elimination rate was 92.85% at a low amount of potassium persulfate (0.075g). The study concludes that the developed approach could be used to efficiently treat abattoir wastewater. VL - 12 IS - 1 ER -
Department of Chemistry, Federal University of Technology, Akure, Nigeria
Information