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Effect of CIGS Absorber Thickness on the Performance of In2S3-Buffered Thin-Film Solar Cells: Role of the MgF2 Antireflection Coating

Received: 3 September 2026     Accepted: 11 September 2026     Published: 27 September 2026
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Abstract

This work numerically investigates, using the Silvaco ATLAS simulator, a thin-film solar cell based on a Cu(In,Ga)Se₂ (CIGS) absorber combined with a non-toxic In2S3 buffer layer replacing conventional CdS, building on an earlier doping-optimization study that identified NA = 3×1016 cm-3 as optimal for both configurations investigated (with and without a MgF2 antireflection coating). At this doping level, two otherwise identical structures, one with MgF2 and one without, are compared to isolate the effect of CIGS absorber thickness (0.5 to 4 µm) on Jsc, Voc, FF and η. Efficiency increases monotonically with thickness, reaching 24.7% with MgF2 and 21.93% without at 4 µm, a nearly constant relative gain of about 12.6% attributable almost entirely to the increase in short-circuit current. The analysis also tracks the effective series (Rs) and shunt (Rsh) resistances extracted from the simulated J–V curves to clarify the mechanism behind the improvement of the fill factor with thickness. The decrease in Rs and increase in Rsh are consistent with reduced electrical losses in thicker absorbers, though these values are read as effective electrical descriptors rather than direct proof of a microstructural change, since no grain-boundary or defect-density model was varied with thickness. A marginal-gain analysis of the full thickness interval, combined with a relative active-material-use analysis, identifies 2–3 µm with MgF2 as the best trade-off between performance and material use. A particularly compact illustration is that a 1 µm CIGS cell with MgF2 (η = 22.17%) already outperforms a 4 µm cell without MgF2 (η = 21.93%), using only a quarter of the absorber volume, showing that improved front-surface optical management can compensate for a substantial reduction in absorber thickness.

Published in Engineering and Applied Sciences (Volume 11, Issue 5)
DOI 10.11648/j.eas.20261105.12
Page(s) 164-178
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2026. Published by Science Publishing Group

Keywords

CIGS, In2S3, MgF2 Antireflection Coating, Absorber Thickness, Series Resistance Rs, Shunt Resistance Rsh, Silvaco ATLAS, Thin-Film Solar Cells

References
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Cite This Article
  • APA Style

    Sow, P. L. T., Goudiaby, C. T., Ngom, A., Faye, J. J., Mohamed-Yahya, A., et al. (2026). Effect of CIGS Absorber Thickness on the Performance of In2S3-Buffered Thin-Film Solar Cells: Role of the MgF2 Antireflection Coating. Engineering and Applied Sciences, 11(5), 164-178. https://doi.org/10.11648/j.eas.20261105.12

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    ACS Style

    Sow, P. L. T.; Goudiaby, C. T.; Ngom, A.; Faye, J. J.; Mohamed-Yahya, A., et al. Effect of CIGS Absorber Thickness on the Performance of In2S3-Buffered Thin-Film Solar Cells: Role of the MgF2 Antireflection Coating. Eng. Appl. Sci. 2026, 11(5), 164-178. doi: 10.11648/j.eas.20261105.12

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    AMA Style

    Sow PLT, Goudiaby CT, Ngom A, Faye JJ, Mohamed-Yahya A, et al. Effect of CIGS Absorber Thickness on the Performance of In2S3-Buffered Thin-Film Solar Cells: Role of the MgF2 Antireflection Coating. Eng Appl Sci. 2026;11(5):164-178. doi: 10.11648/j.eas.20261105.12

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  • @article{10.11648/j.eas.20261105.12,
      author = {Papa Lat Tabara Sow and Cheick Tidiane Goudiaby and Alioune Ngom and Jacques Joachim Faye and Ahmed Mohamed-Yahya and Mamadou Lamine Samb},
      title = {Effect of CIGS Absorber Thickness on the Performance of In2S3-Buffered Thin-Film Solar Cells: Role of the MgF2 Antireflection Coating},
      journal = {Engineering and Applied Sciences},
      volume = {11},
      number = {5},
      pages = {164-178},
      doi = {10.11648/j.eas.20261105.12},
      url = {https://doi.org/10.11648/j.eas.20261105.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.eas.20261105.12},
      abstract = {This work numerically investigates, using the Silvaco ATLAS simulator, a thin-film solar cell based on a Cu(In,Ga)Se₂ (CIGS) absorber combined with a non-toxic In2S3 buffer layer replacing conventional CdS, building on an earlier doping-optimization study that identified NA = 3×1016 cm-3 as optimal for both configurations investigated (with and without a MgF2 antireflection coating). At this doping level, two otherwise identical structures, one with MgF2 and one without, are compared to isolate the effect of CIGS absorber thickness (0.5 to 4 µm) on Jsc, Voc, FF and η. Efficiency increases monotonically with thickness, reaching 24.7% with MgF2 and 21.93% without at 4 µm, a nearly constant relative gain of about 12.6% attributable almost entirely to the increase in short-circuit current. The analysis also tracks the effective series (Rs) and shunt (Rsh) resistances extracted from the simulated J–V curves to clarify the mechanism behind the improvement of the fill factor with thickness. The decrease in Rs and increase in Rsh are consistent with reduced electrical losses in thicker absorbers, though these values are read as effective electrical descriptors rather than direct proof of a microstructural change, since no grain-boundary or defect-density model was varied with thickness. A marginal-gain analysis of the full thickness interval, combined with a relative active-material-use analysis, identifies 2–3 µm with MgF2 as the best trade-off between performance and material use. A particularly compact illustration is that a 1 µm CIGS cell with MgF2 (η = 22.17%) already outperforms a 4 µm cell without MgF2 (η = 21.93%), using only a quarter of the absorber volume, showing that improved front-surface optical management can compensate for a substantial reduction in absorber thickness.},
     year = {2026}
    }
    

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  • TY  - JOUR
    T1  - Effect of CIGS Absorber Thickness on the Performance of In2S3-Buffered Thin-Film Solar Cells: Role of the MgF2 Antireflection Coating
    AU  - Papa Lat Tabara Sow
    AU  - Cheick Tidiane Goudiaby
    AU  - Alioune Ngom
    AU  - Jacques Joachim Faye
    AU  - Ahmed Mohamed-Yahya
    AU  - Mamadou Lamine Samb
    Y1  - 2026/09/27
    PY  - 2026
    N1  - https://doi.org/10.11648/j.eas.20261105.12
    DO  - 10.11648/j.eas.20261105.12
    T2  - Engineering and Applied Sciences
    JF  - Engineering and Applied Sciences
    JO  - Engineering and Applied Sciences
    SP  - 164
    EP  - 178
    PB  - Science Publishing Group
    SN  - 2575-1468
    UR  - https://doi.org/10.11648/j.eas.20261105.12
    AB  - This work numerically investigates, using the Silvaco ATLAS simulator, a thin-film solar cell based on a Cu(In,Ga)Se₂ (CIGS) absorber combined with a non-toxic In2S3 buffer layer replacing conventional CdS, building on an earlier doping-optimization study that identified NA = 3×1016 cm-3 as optimal for both configurations investigated (with and without a MgF2 antireflection coating). At this doping level, two otherwise identical structures, one with MgF2 and one without, are compared to isolate the effect of CIGS absorber thickness (0.5 to 4 µm) on Jsc, Voc, FF and η. Efficiency increases monotonically with thickness, reaching 24.7% with MgF2 and 21.93% without at 4 µm, a nearly constant relative gain of about 12.6% attributable almost entirely to the increase in short-circuit current. The analysis also tracks the effective series (Rs) and shunt (Rsh) resistances extracted from the simulated J–V curves to clarify the mechanism behind the improvement of the fill factor with thickness. The decrease in Rs and increase in Rsh are consistent with reduced electrical losses in thicker absorbers, though these values are read as effective electrical descriptors rather than direct proof of a microstructural change, since no grain-boundary or defect-density model was varied with thickness. A marginal-gain analysis of the full thickness interval, combined with a relative active-material-use analysis, identifies 2–3 µm with MgF2 as the best trade-off between performance and material use. A particularly compact illustration is that a 1 µm CIGS cell with MgF2 (η = 22.17%) already outperforms a 4 µm cell without MgF2 (η = 21.93%), using only a quarter of the absorber volume, showing that improved front-surface optical management can compensate for a substantial reduction in absorber thickness.
    VL  - 11
    IS  - 5
    ER  - 

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