Quantum-Classical Electron as an Organizing Principle in Nature

Vladimir Valentinovich Egorov

doi:doi:10.11648/j.ijsts.20200804.12

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Quantum-Classical Electron as an Organizing Principle in Nature

Vladimir Valentinovich Egorov

Published in International Journal of Science, Technology and Society (Volume 8, Issue 4)

Received: 27 June 2020 Accepted: 21 July 2020 Published: 17 August 2020

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Abstract

We are introducing briefly to the new theory of “quantum” transitions in molecular and chemical physics — quantum-classical mechanics, in which an electron behaves dynamically in two ways: both as a quantum and as a classical elementary particle. Namely, in the initial and final adiabatic states of molecular “quantum” transitions, the light electron exhibits its quantum properties. On the contrary, in the transient molecular state, the electron, provoking the so-called dozy chaos in the vibrational motion of very heavy nuclei “in order” to shift the equilibrium positions of their vibrations to new positions corresponding to the new distribution of the electron charge, because of the continuous energy spectrum in the transient state, manifests itself as a classical elementary particle. The article discusses mainly studied and some promising applications of the organizing role of an electron in nature. Among the well-studied applications, the quantum-classical organization of optical absorption band shapes in polymethine dyes and their J-aggregates is discussed. For example, the well-known narrow and intense J-band of J-aggregates is one of the striking examples of the implementation of the so-called Egorov resonance, in which the motion of the reorganization of the nuclei of the environmental medium significantly contributes to the electron transition in the optical pi-electron chromophore of J-aggregates. This effect can also be interpreted as the transfer of dozy chaos from the peak of the J-band into its wing by a chaotic motion of the quantum-classical pi-electron state of the J-chromophore. The dynamic role of the quantum-classical electron in the joint organization of the absorption and luminescence spectra, and an extension of quantum-classical mechanics to nonlinear optical processes are discussed. The probable leading role of quantum-classical electrons in the evolution of molecular matter and possibility of applications of quantum-classical mechanics to the study of cancer and viruses are discussed as a future research perspective.

Published in	International Journal of Science, Technology and Society (Volume 8, Issue 4)
DOI	10.11648/j.ijsts.20200804.12
Page(s)	83-93
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Molecular Quantum Transitions, Dozy Chaos, Quantum-Classical Mechanics, Optical Spectra, Polymethine Dyes, Bioimaging, Cancer, Virus

References

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Vladimir Valentinovich Egorov. (2020). Quantum-Classical Electron as an Organizing Principle in Nature. International Journal of Science, Technology and Society, 8(4), 83-93. https://doi.org/10.11648/j.ijsts.20200804.12

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Vladimir Valentinovich Egorov. Quantum-Classical Electron as an Organizing Principle in Nature. Int. J. Sci. Technol. Soc. 2020, 8(4), 83-93. doi: 10.11648/j.ijsts.20200804.12

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Vladimir Valentinovich Egorov. Quantum-Classical Electron as an Organizing Principle in Nature. Int J Sci Technol Soc. 2020;8(4):83-93. doi: 10.11648/j.ijsts.20200804.12

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@article{10.11648/j.ijsts.20200804.12,
  author = {Vladimir Valentinovich Egorov},
  title = {Quantum-Classical Electron as an Organizing Principle in Nature},
  journal = {International Journal of Science, Technology and Society},
  volume = {8},
  number = {4},
  pages = {83-93},
  doi = {10.11648/j.ijsts.20200804.12},
  url = {https://doi.org/10.11648/j.ijsts.20200804.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijsts.20200804.12},
  abstract = {We are introducing briefly to the new theory of “quantum” transitions in molecular and chemical physics — quantum-classical mechanics, in which an electron behaves dynamically in two ways: both as a quantum and as a classical elementary particle. Namely, in the initial and final adiabatic states of molecular “quantum” transitions, the light electron exhibits its quantum properties. On the contrary, in the transient molecular state, the electron, provoking the so-called dozy chaos in the vibrational motion of very heavy nuclei “in order” to shift the equilibrium positions of their vibrations to new positions corresponding to the new distribution of the electron charge, because of the continuous energy spectrum in the transient state, manifests itself as a classical elementary particle. The article discusses mainly studied and some promising applications of the organizing role of an electron in nature. Among the well-studied applications, the quantum-classical organization of optical absorption band shapes in polymethine dyes and their J-aggregates is discussed. For example, the well-known narrow and intense J-band of J-aggregates is one of the striking examples of the implementation of the so-called Egorov resonance, in which the motion of the reorganization of the nuclei of the environmental medium significantly contributes to the electron transition in the optical pi-electron chromophore of J-aggregates. This effect can also be interpreted as the transfer of dozy chaos from the peak of the J-band into its wing by a chaotic motion of the quantum-classical pi-electron state of the J-chromophore. The dynamic role of the quantum-classical electron in the joint organization of the absorption and luminescence spectra, and an extension of quantum-classical mechanics to nonlinear optical processes are discussed. The probable leading role of quantum-classical electrons in the evolution of molecular matter and possibility of applications of quantum-classical mechanics to the study of cancer and viruses are discussed as a future research perspective.},
 year = {2020}
}

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TY  - JOUR
T1  - Quantum-Classical Electron as an Organizing Principle in Nature
AU  - Vladimir Valentinovich Egorov
Y1  - 2020/08/17
PY  - 2020
N1  - https://doi.org/10.11648/j.ijsts.20200804.12
DO  - 10.11648/j.ijsts.20200804.12
T2  - International Journal of Science, Technology and Society
JF  - International Journal of Science, Technology and Society
JO  - International Journal of Science, Technology and Society
SP  - 83
EP  - 93
PB  - Science Publishing Group
SN  - 2330-7420
UR  - https://doi.org/10.11648/j.ijsts.20200804.12
AB  - We are introducing briefly to the new theory of “quantum” transitions in molecular and chemical physics — quantum-classical mechanics, in which an electron behaves dynamically in two ways: both as a quantum and as a classical elementary particle. Namely, in the initial and final adiabatic states of molecular “quantum” transitions, the light electron exhibits its quantum properties. On the contrary, in the transient molecular state, the electron, provoking the so-called dozy chaos in the vibrational motion of very heavy nuclei “in order” to shift the equilibrium positions of their vibrations to new positions corresponding to the new distribution of the electron charge, because of the continuous energy spectrum in the transient state, manifests itself as a classical elementary particle. The article discusses mainly studied and some promising applications of the organizing role of an electron in nature. Among the well-studied applications, the quantum-classical organization of optical absorption band shapes in polymethine dyes and their J-aggregates is discussed. For example, the well-known narrow and intense J-band of J-aggregates is one of the striking examples of the implementation of the so-called Egorov resonance, in which the motion of the reorganization of the nuclei of the environmental medium significantly contributes to the electron transition in the optical pi-electron chromophore of J-aggregates. This effect can also be interpreted as the transfer of dozy chaos from the peak of the J-band into its wing by a chaotic motion of the quantum-classical pi-electron state of the J-chromophore. The dynamic role of the quantum-classical electron in the joint organization of the absorption and luminescence spectra, and an extension of quantum-classical mechanics to nonlinear optical processes are discussed. The probable leading role of quantum-classical electrons in the evolution of molecular matter and possibility of applications of quantum-classical mechanics to the study of cancer and viruses are discussed as a future research perspective.
VL  - 8
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Vladimir Valentinovich Egorov

Russian Academy of Sciences, FSRC “Crystallography and Photonics”, Photochemistry Center, Moscow, Russian Federation

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Vladimir Valentinovich Egorov. (2020). Quantum-Classical Electron as an Organizing Principle in Nature. International Journal of Science, Technology and Society, 8(4), 83-93. https://doi.org/10.11648/j.ijsts.20200804.12

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Vladimir Valentinovich Egorov. Quantum-Classical Electron as an Organizing Principle in Nature. Int. J. Sci. Technol. Soc. 2020, 8(4), 83-93. doi: 10.11648/j.ijsts.20200804.12

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Vladimir Valentinovich Egorov. Quantum-Classical Electron as an Organizing Principle in Nature. Int J Sci Technol Soc. 2020;8(4):83-93. doi: 10.11648/j.ijsts.20200804.12

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@article{10.11648/j.ijsts.20200804.12,
  author = {Vladimir Valentinovich Egorov},
  title = {Quantum-Classical Electron as an Organizing Principle in Nature},
  journal = {International Journal of Science, Technology and Society},
  volume = {8},
  number = {4},
  pages = {83-93},
  doi = {10.11648/j.ijsts.20200804.12},
  url = {https://doi.org/10.11648/j.ijsts.20200804.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijsts.20200804.12},
  abstract = {We are introducing briefly to the new theory of “quantum” transitions in molecular and chemical physics — quantum-classical mechanics, in which an electron behaves dynamically in two ways: both as a quantum and as a classical elementary particle. Namely, in the initial and final adiabatic states of molecular “quantum” transitions, the light electron exhibits its quantum properties. On the contrary, in the transient molecular state, the electron, provoking the so-called dozy chaos in the vibrational motion of very heavy nuclei “in order” to shift the equilibrium positions of their vibrations to new positions corresponding to the new distribution of the electron charge, because of the continuous energy spectrum in the transient state, manifests itself as a classical elementary particle. The article discusses mainly studied and some promising applications of the organizing role of an electron in nature. Among the well-studied applications, the quantum-classical organization of optical absorption band shapes in polymethine dyes and their J-aggregates is discussed. For example, the well-known narrow and intense J-band of J-aggregates is one of the striking examples of the implementation of the so-called Egorov resonance, in which the motion of the reorganization of the nuclei of the environmental medium significantly contributes to the electron transition in the optical pi-electron chromophore of J-aggregates. This effect can also be interpreted as the transfer of dozy chaos from the peak of the J-band into its wing by a chaotic motion of the quantum-classical pi-electron state of the J-chromophore. The dynamic role of the quantum-classical electron in the joint organization of the absorption and luminescence spectra, and an extension of quantum-classical mechanics to nonlinear optical processes are discussed. The probable leading role of quantum-classical electrons in the evolution of molecular matter and possibility of applications of quantum-classical mechanics to the study of cancer and viruses are discussed as a future research perspective.},
 year = {2020}
}

Copy | Download

TY  - JOUR
T1  - Quantum-Classical Electron as an Organizing Principle in Nature
AU  - Vladimir Valentinovich Egorov
Y1  - 2020/08/17
PY  - 2020
N1  - https://doi.org/10.11648/j.ijsts.20200804.12
DO  - 10.11648/j.ijsts.20200804.12
T2  - International Journal of Science, Technology and Society
JF  - International Journal of Science, Technology and Society
JO  - International Journal of Science, Technology and Society
SP  - 83
EP  - 93
PB  - Science Publishing Group
SN  - 2330-7420
UR  - https://doi.org/10.11648/j.ijsts.20200804.12
AB  - We are introducing briefly to the new theory of “quantum” transitions in molecular and chemical physics — quantum-classical mechanics, in which an electron behaves dynamically in two ways: both as a quantum and as a classical elementary particle. Namely, in the initial and final adiabatic states of molecular “quantum” transitions, the light electron exhibits its quantum properties. On the contrary, in the transient molecular state, the electron, provoking the so-called dozy chaos in the vibrational motion of very heavy nuclei “in order” to shift the equilibrium positions of their vibrations to new positions corresponding to the new distribution of the electron charge, because of the continuous energy spectrum in the transient state, manifests itself as a classical elementary particle. The article discusses mainly studied and some promising applications of the organizing role of an electron in nature. Among the well-studied applications, the quantum-classical organization of optical absorption band shapes in polymethine dyes and their J-aggregates is discussed. For example, the well-known narrow and intense J-band of J-aggregates is one of the striking examples of the implementation of the so-called Egorov resonance, in which the motion of the reorganization of the nuclei of the environmental medium significantly contributes to the electron transition in the optical pi-electron chromophore of J-aggregates. This effect can also be interpreted as the transfer of dozy chaos from the peak of the J-band into its wing by a chaotic motion of the quantum-classical pi-electron state of the J-chromophore. The dynamic role of the quantum-classical electron in the joint organization of the absorption and luminescence spectra, and an extension of quantum-classical mechanics to nonlinear optical processes are discussed. The probable leading role of quantum-classical electrons in the evolution of molecular matter and possibility of applications of quantum-classical mechanics to the study of cancer and viruses are discussed as a future research perspective.
VL  - 8
IS  - 4
ER  -

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