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Geometallurgical Modeling of Complex Fe-Ti-V-Mn Oxide Mineralization: A Processing Strategy for the Gambella-Dembidollo Deposit, Western Ethiopia

Received: 15 October 2025     Accepted: 25 October 2025     Published: 3 December 2025
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Abstract

A groundbreaking geometallurgical reevaluation of a complex Iron-Titanium-Vanadium-Manganese (Fe-Ti-V-Mn) oxide mineralization located in the Gambella-Dembidollo region of Western Ethiopia has been carried out through this research. The research is substantiated by comprehensive archival mineralogical and geochemical data from a primary technical work done by Stern Lapajne (1985). The principal mineral resource assemblage which consists of iron (Fe2O3), iron (Fe3O4), and titanium (FeTiO3) has a close relationship with manganese (Mn3O4) that is very difficult to process and that was the major reason of its earlier classification as sub-economic. This research presents four geometallurgical constraints that stem from the mineralogy: (1) the fine-grained, solid-solution texture of ilmenite within haematite, which makes titanium liberation difficult; (2) the complete incorporation of vanadium within the magnetite crystal lattice, hence its recovery being dependent on magnetic separation efficiency; (3) the complicated association of the manganese-rich phase (hausmannite) with the iron oxide fraction; and (4) the overall low grade of the mineral deposit, which necessitates the implementation of an efficient pre-concentration scheme to secure the project’s economic feasibility. A predictive processing flowsheet is built upon these constraining factors, along with a multi-stage recovery process. The process starts with Low-Intensity Magnetic Separation (LIMS) to capture the V-bearing magnetite, and then the non-magnetic fraction is subject to an intensive liberation step with ultrafine grinding. The next step is to use High-Intensity Magnetic Separation (HIMS) or differential flotation to get ready-to-sell ilmenite and hausmannite concentrates. The analysis done in the study brings to light that despite the deposit being intermittent and complex in mineralogy, such a geometallurgy-enabled, sequential recovery process could make the metal yield of multiple elements the highest possible. The research presents a useful model for evaluation of such complicated oxide systems worldwide, and it clearly shows that the combination of mineralogical and process analysis can be a powerful tool in making a profit out of difficult mineral resources.

Published in Journal of Energy, Environmental & Chemical Engineering (Volume 10, Issue 4)
DOI 10.11648/j.jeece.20251004.11
Page(s) 99-107
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2025. Published by Science Publishing Group

Keywords

Geometallurgy, Mineral Processing, Vanadium Recovery, Ilmenite, Hausmannite, Magnetic Separation, Flotation, Ethiopia

References
[1] Kazak, O., Aslan, N. and Canbazoğlu, M. A review of the metallurgy of vanadium. In: Proceedings of the 15th International Mineral Processing Symposium. Istanbul, Turkey, 2016, pp. 1–10.
[2] Sandu, A. V., Achitei, D. C., Perju, M. C. and Burduhos-Nergis, D. D. Perspective Chapter: Titanium–A Versatile Metal in Modern Applications. In: Titanium-Based Alloys-Characteristics and Applications: Characteristics and Applications. 2024, p. 3.
[3] Duchesne, J. C. Fe-Ti deposits in Rogaland anorthosites (South Norway): Geochemical characteristics and problems of interpretation. Mineralium Deposita, 1999, 34(2), pp. 182–198.
[4] Wills, B. A. and Finch, J. A. Wills' Mineral Processing Technology: An Introduction to the Practical Aspects of Ore Treatment and Mineral Recovery. 8th ed. Butterworth-Heinemann, 2016.
[5] Stern Lapajne, S. Geological Survey and Mineral Resource Assessment of the Gambella-Dembidollo Pegmatite Fields. Internal Technical Report No. 85-12. RUDIS Mining Association, 1985.
[6] Duhovnik, J. Geochemical Analysis of Oxide and Silicate Samples from the Gambella-Dembidollo Region. Analytical Report. RUDIS Mining Association, 1985.
[7] Williams, S. R. and Richardson, J. M. Geometallurgical mapping: A new approach that reduces technical risk. In: Proceedings of the 36th Annual Canadian Mineral Processors Conference. 2004, pp. 241-268.
[8] Moskalyk, R. R. and Alfantazi, A. M. Processing of vanadium: a review. Minerals Engineering, 2003, 16(9), pp. 793-805.
[9] Gaudin, L. Extraction of Vanadium from New Zealand Titanomagnetite Sand and Vanadium Recovery Concentrate. Doctoral dissertation. Open Access Te Herenga Waka-Victoria University of Wellington, 2022.
[10] Gao, Z., Li, C., Sun, Y. and Bai, S. Flotation and separation of ilmenite from titanaugite using a new hydroxamic acid collector. Minerals Engineering, 2018, 122, pp. 267–273.
[11] Zhang, L. and Chen, T. Selective separation of hausmannite from vanadiferous magnetite using high-intensity magnetic separation. Minerals Engineering, 2020, 152, 106336.
[12] Gu, F., Zhang, Y., Su, Z., Liu, G. and Li, Y. A novel process for the recovery of vanadium from vanadium-bearing magnetite ore. Minerals Engineering, 2019, 138, pp. 124-130.
[13] Chen, X. and Chen, T. Process mineralogy as a key tool in the recovery of ilmenite from complex para-magnetics. Journal of Materials Research and Technology, 2021, 15, pp. 4567-4577.
[14] Li, Y., Wang, J. and Zhang, L. Optimization of titanium concentrate grade from a complex iron ore via ultrafine grinding and advanced separation. Minerals Engineering, 2020, 155, 106442.
[15] Kumar, A., Filippov, L. O. and Angadi, S. I. Challenges and strategies in the beneficiation of low-grade ferromanganese ores. Minerals Engineering, 2022, 189, 107891.
[16] Willis, B. A. and Napier-Munn, T. J. Mineral Processing Economics: Valuing Flexibility and Multi-Product Flowsheets. SME, 2018.
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    Mekonen, G., Tesfaye, W. (2025). Geometallurgical Modeling of Complex Fe-Ti-V-Mn Oxide Mineralization: A Processing Strategy for the Gambella-Dembidollo Deposit, Western Ethiopia. Journal of Energy, Environmental & Chemical Engineering, 10(4), 99-107. https://doi.org/10.11648/j.jeece.20251004.11

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    ACS Style

    Mekonen, G.; Tesfaye, W. Geometallurgical Modeling of Complex Fe-Ti-V-Mn Oxide Mineralization: A Processing Strategy for the Gambella-Dembidollo Deposit, Western Ethiopia. J. Energy Environ. Chem. Eng. 2025, 10(4), 99-107. doi: 10.11648/j.jeece.20251004.11

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    AMA Style

    Mekonen G, Tesfaye W. Geometallurgical Modeling of Complex Fe-Ti-V-Mn Oxide Mineralization: A Processing Strategy for the Gambella-Dembidollo Deposit, Western Ethiopia. J Energy Environ Chem Eng. 2025;10(4):99-107. doi: 10.11648/j.jeece.20251004.11

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  • @article{10.11648/j.jeece.20251004.11,
      author = {Gutema Mekonen and Wakjira Tesfaye},
      title = {Geometallurgical Modeling of Complex Fe-Ti-V-Mn Oxide Mineralization: A Processing Strategy for the Gambella-Dembidollo Deposit, Western Ethiopia
    },
      journal = {Journal of Energy, Environmental & Chemical Engineering},
      volume = {10},
      number = {4},
      pages = {99-107},
      doi = {10.11648/j.jeece.20251004.11},
      url = {https://doi.org/10.11648/j.jeece.20251004.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jeece.20251004.11},
      abstract = {A groundbreaking geometallurgical reevaluation of a complex Iron-Titanium-Vanadium-Manganese (Fe-Ti-V-Mn) oxide mineralization located in the Gambella-Dembidollo region of Western Ethiopia has been carried out through this research. The research is substantiated by comprehensive archival mineralogical and geochemical data from a primary technical work done by Stern Lapajne (1985). The principal mineral resource assemblage which consists of iron (Fe2O3), iron (Fe3O4), and titanium (FeTiO3) has a close relationship with manganese (Mn3O4) that is very difficult to process and that was the major reason of its earlier classification as sub-economic. This research presents four geometallurgical constraints that stem from the mineralogy: (1) the fine-grained, solid-solution texture of ilmenite within haematite, which makes titanium liberation difficult; (2) the complete incorporation of vanadium within the magnetite crystal lattice, hence its recovery being dependent on magnetic separation efficiency; (3) the complicated association of the manganese-rich phase (hausmannite) with the iron oxide fraction; and (4) the overall low grade of the mineral deposit, which necessitates the implementation of an efficient pre-concentration scheme to secure the project’s economic feasibility. A predictive processing flowsheet is built upon these constraining factors, along with a multi-stage recovery process. The process starts with Low-Intensity Magnetic Separation (LIMS) to capture the V-bearing magnetite, and then the non-magnetic fraction is subject to an intensive liberation step with ultrafine grinding. The next step is to use High-Intensity Magnetic Separation (HIMS) or differential flotation to get ready-to-sell ilmenite and hausmannite concentrates. The analysis done in the study brings to light that despite the deposit being intermittent and complex in mineralogy, such a geometallurgy-enabled, sequential recovery process could make the metal yield of multiple elements the highest possible. The research presents a useful model for evaluation of such complicated oxide systems worldwide, and it clearly shows that the combination of mineralogical and process analysis can be a powerful tool in making a profit out of difficult mineral resources.
    },
     year = {2025}
    }
    

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  • TY  - JOUR
    T1  - Geometallurgical Modeling of Complex Fe-Ti-V-Mn Oxide Mineralization: A Processing Strategy for the Gambella-Dembidollo Deposit, Western Ethiopia
    
    AU  - Gutema Mekonen
    AU  - Wakjira Tesfaye
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    PY  - 2025
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    DO  - 10.11648/j.jeece.20251004.11
    T2  - Journal of Energy, Environmental & Chemical Engineering
    JF  - Journal of Energy, Environmental & Chemical Engineering
    JO  - Journal of Energy, Environmental & Chemical Engineering
    SP  - 99
    EP  - 107
    PB  - Science Publishing Group
    SN  - 2637-434X
    UR  - https://doi.org/10.11648/j.jeece.20251004.11
    AB  - A groundbreaking geometallurgical reevaluation of a complex Iron-Titanium-Vanadium-Manganese (Fe-Ti-V-Mn) oxide mineralization located in the Gambella-Dembidollo region of Western Ethiopia has been carried out through this research. The research is substantiated by comprehensive archival mineralogical and geochemical data from a primary technical work done by Stern Lapajne (1985). The principal mineral resource assemblage which consists of iron (Fe2O3), iron (Fe3O4), and titanium (FeTiO3) has a close relationship with manganese (Mn3O4) that is very difficult to process and that was the major reason of its earlier classification as sub-economic. This research presents four geometallurgical constraints that stem from the mineralogy: (1) the fine-grained, solid-solution texture of ilmenite within haematite, which makes titanium liberation difficult; (2) the complete incorporation of vanadium within the magnetite crystal lattice, hence its recovery being dependent on magnetic separation efficiency; (3) the complicated association of the manganese-rich phase (hausmannite) with the iron oxide fraction; and (4) the overall low grade of the mineral deposit, which necessitates the implementation of an efficient pre-concentration scheme to secure the project’s economic feasibility. A predictive processing flowsheet is built upon these constraining factors, along with a multi-stage recovery process. The process starts with Low-Intensity Magnetic Separation (LIMS) to capture the V-bearing magnetite, and then the non-magnetic fraction is subject to an intensive liberation step with ultrafine grinding. The next step is to use High-Intensity Magnetic Separation (HIMS) or differential flotation to get ready-to-sell ilmenite and hausmannite concentrates. The analysis done in the study brings to light that despite the deposit being intermittent and complex in mineralogy, such a geometallurgy-enabled, sequential recovery process could make the metal yield of multiple elements the highest possible. The research presents a useful model for evaluation of such complicated oxide systems worldwide, and it clearly shows that the combination of mineralogical and process analysis can be a powerful tool in making a profit out of difficult mineral resources.
    
    VL  - 10
    IS  - 4
    ER  - 

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