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Recent Advance and Future Perspective of 2D MXene for Energy Storage: Mini Review

Received: 8 October 2022    Accepted: 10 November 2022    Published: 8 December 2022
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Abstract

MXene is deemed to be one of the best attentive materials in an extensive range of applications due to its stupendous optical, electronic, thermal, and mechanical properties. Different MXene-based nanomaterials with extraordinary characteristics have been proposed, prepared, and practiced as a catalyst due to its two-dimensional (2D) structure, large specific surface area, facile decoration, and high adsorption capacity. Transition metal carbides and/or nitrides (MXenes), a developing class of 2D layer-structure compounds, are being given a lot of attention as one of the most promising classes of energy storage materials due to their numerous advantages, including high electrical conductivity, tunable layer structure, small band gap, and functionalized redox active surface. Bottom-up synthesis, which uses chemical vapor deposition, a template approach, and pulsed laser deposition with plasma enhancement, and top-down synthesis, which uses etching and exfoliation, are the two basic types of synthesis. In this review paper, more than 56 articles where reviewed on 2D MXene materials along with their application in energy storage battery. Numerous applications for energy storage exist for nanomaterials based on (2D) MXene. Even though 2D MXene could have some drawbacks, a lot of research has gone into nanoengineering these 2D materials to improve their functionality for real-world applications. Recent literature has described various uses for 2D MXene materials in lithium-ion batteries, sodium-ion batteries, lithium-sulfur batteries, and supercapacitors. To progress in facilitating their industrial application, the difficulty and prospective future are also examined.

Published in Nanoscience and Nanometrology (Volume 8, Issue 2)
DOI 10.11648/j.nsnm.20220802.11
Page(s) 15-22
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

2D Materials, Etching, Energy Storage, MXenes, Synthesis

References
[1] Das P, Wu ZS. MXene for energy storage: Present status and future perspectives. JPhys Energy. 2020; 2 (3).
[2] Nan J, Guo X, Xiao J, Li X, Chen W, Wu W, et al. Nanoengineering of 2D MXene-Based Materials for Energy Storage Applications. Small. 2021; 17 (9).
[3] Rahman UU, Humayun M, Ghani U, Usman M, Ullah H, Khan A, et al. MXenes as Emerging Materials: Synthesis, Properties, and Applications. Molecules. 2022; 27 (15).
[4] Zhao X, Radovic M, Green MJ. Synthesizing MXene Nanosheets by Water-free Etching. Chem [Internet]. 2020; 6 (3): 544–6. Available from: https://doi.org/10.1016/j.chempr.2020.02.013
[5] Sun ZM. Progress in research and development on MAX phases: A family of layered ternary compounds. Int Mater Rev. 2011; 56 (3): 143–66.
[6] Högberg H, Hultman L, Emmerlich J, Joelsson T, Eklund P, Molina-Aldareguia JM, et al. Growth and characterization of MAX-phase thin films. Surf Coatings Technol. 2005; 193 (1-3 SPEC. ISS.): 6–10.
[7] Wu M, He Y, Wang L, Xia Q, Zhou A. Synthesis and electrochemical properties of V2C MXene by etching in opened/closed environments. J Adv Ceram. 2020; 9 (6): 749–58.
[8] Vaia RA, Jawaid A, Hassan A, Neher G, Nepal D, Pachter R, et al. Halogen etch of Ti3AlC2 MAX phase for mxene fabrication. ACS Nano. 2021; 15 (2): 2771–7.
[9] Kannan K, Sadasivuni KK, Abdullah AM, Kumar B. Current trends in MXene-based nanomaterials for energy storage and conversion system: A mini review. Catalysts. 2020; 10 (5): 1–28.
[10] Verger L, Xu C, Natu V, Cheng HM, Ren W, Barsoum MW. Overview of the synthesis of MXenes and other ultrathin 2D transition metal carbides and nitrides. Curr Opin Solid State Mater Sci. 2019; 23 (3): 149–63.
[11] Kumar JA, Prakash P, Krithiga T, Amarnath DJ, Premkumar J, Rajamohan N, et al. Methods of synthesis, characteristics, and environmental applications of MXene: A comprehensive review. Chemosphere [Internet]. 2022; 286 (P1): 131607. Available from: https://doi.org/10.1016/j.chemosphere.2021.131607
[12] Lim KRG, Shekhirev M, Wyatt BC, Anasori B, Gogotsi Y, Seh ZW. Fundamentals of MXene synthesis. Nat Synth. 2022; 1 (8): 601–14.
[13] Naguib M, Mashtalir O, Carle J, Presser V, Lu J, Hultman L, et al. Two-dimensional transition metal carbides. ACS Nano. 2012; 6 (2): 1322–31.
[14] Zhou C, Zhao X, Xiong Y, Tang Y, Ma X, Tao Q, et al. A review of etching methods of MXene and applications of MXene conductive hydrogels. Eur Polym J [Internet]. 2022; 167 (January): 111063. Available from: https://doi.org/10.1016/j.eurpolymj.2022.111063
[15] Wu M, Wang B, Hu Q, Wang L, Zhou A. The synthesis process and thermal stability of V2C MXene. Materials (Basel). 2018; 11 (11): 8–11.
[16] Alhabeb M, Maleski K, Mathis TS, Sarycheva A, Hatter CB, Uzun S, et al. Selective Etching of Silicon from Ti 3 SiC 2 (MAX) To Obtain 2D Titanium Carbide (MXene). Angew Chemie. 2018; 130 (19): 5542–6.
[17] Pazniak A, Bazhin P, Shplis N, Kolesnikov E, Shchetinin I, Komissarov A, et al. Ti3C2Tx MXene characterization produced from SHS-ground Ti3AlC2. Mater Des [Internet]. 2019; 183: 108143. Available from: https://doi.org/10.1016/j.matdes.2019.108143
[18] Ronchi RM, Arantes JT, Santos SF. Synthesis, structure, properties and applications of MXenes: Current status and perspectives. Ceram Int [Internet]. 2019; 45 (15): 18167–88. Available from: https://doi.org/10.1016/j.ceramint.2019.06.114
[19] Feng A, Yu Y, Wang Y, Jiang F, Yu Y, Mi L, et al. Two-dimensional MXene Ti3C2 produced by exfoliation of Ti3AlC2. Mater Des. 2017; 114: 161–6.
[20] Ghidiu M, Lukatskaya MR, Zhao MQ, Gogotsi Y, Barsoum MW. Conductive two-dimensional titanium carbide “clay” with high volumetric capacitance. Nature [Internet]. 2015; 516 (7529): 78–81. Available from: http://dx.doi.org/10.1038/nature13970
[21] Xu C, Wang L, Liu Z, Chen L, Guo J, Kang N, et al. Large-area high-quality 2D ultrathin Mo2C superconducting crystals. Nat Mater. 2015; 14 (11): 1135–41.
[22] Wang QH, Kalantar-Zadeh K, Kis A, Coleman JN, Strano MS. Electronics and optoelectronics of two-dimensional transition metal dichalcogenides. Nat Nanotechnol. 2012; 7 (11): 699–712.
[23] Fu B, Sun J, Wang C, Shang C, Xu L, Li J, et al. MXenes: Synthesis, Optical Properties, and Applications in Ultrafast Photonics. Small. 2021; 17 (11): 1–23.
[24] Zhang S, Ying H, Guo R, Yang WT, Han WQ. Vapor deposition red phosphorus to prepare nitrogen-doped Ti3C2Tx mxenes composites for lithium-ion batteries. J Phys Chem Lett. 2019; 10 (21): 6446–54.
[25] Xiao X, Yu H, Jin H, Wu M, Fang Y, Sun J, et al. Salt-Templated Synthesis of 2D Metallic MoN and Other Nitrides. ACS Nano. 2017; 11 (2): 2180–6.
[26] Zhang F, Zhang Z, Wang H, Chan CH, Chan NY, Chen XX, et al. Plasma-enhanced pulsed-laser deposition of single-crystalline Mo2C ultrathin superconducting films. Phys Rev Mater. 2017; 1 (3): 1–8.
[27] Kayali E, Vahidmohammadi A, Orangi J, Beidaghi M. Controlling the Dimensions of 2D MXenes for Ultrahigh-Rate Pseudocapacitive Energy Storage. ACS Appl Mater Interfaces. 2018; 10 (31): 25949–54.
[28] Yao LH, Cao WQ, Shu JC, Cao MS, Sun X Di. Tailoring adsorption for tunable lithium ion storage and devices. Chem Eng J. 2021; 413 (July): 127428.
[29] Li X, Zeng C, Fan G. Ultrafast hydrogen generation from the hydrolysis of ammonia borane catalyzed by highly efficient bimetallic RuNi nanoparticles stabilized on Ti3C2X2 (X = OH and/or F). Int J Hydrogen Energy. 2015; 40 (10): 3883–91.
[30] Ma TY, Cao JL, Jaroniec M, Qiao SZ. Interacting carbon nitride and titanium carbide nanosheets for high-performance oxygen evolution. Angew Chemie - Int Ed. 2016; 55 (3): 1138–42.
[31] Guo J, Peng Q, Fu H, Zou G, Zhang Q. Heavy-Metal Adsorption Behavior of Two-Dimensional Alkalization-Intercalated MXene by First-Principles Calculations. J Phys Chem C. 2015; 119 (36): 20923–30.
[32] Chen J, Chen K, Tong D, Huang Y, Zhang J, Xue J, et al. CO2 and temperature dual responsive “smart” MXene phases. Chem Commun. 2015; 51 (2): 314–7.
[33] Sang X, Xie Y, Lin MW, Alhabeb M, Van Aken KL, Gogotsi Y, et al. Atomic defects in monolayer titanium carbide (Ti3C2Tx) MXene. ACS Nano. 2016; 10 (10): 9193–200.
[34] Yu M, Wang Z, Liu J, Sun F, Yang P, Qiu J. A hierarchically porous and hydrophilic 3D nickel–iron/MXene electrode for accelerating oxygen and hydrogen evolution at high current densities. Nano Energy. 2019; 63 (July): 103880.
[35] Eames C, Islam MS. Ion intercalation into two-dimensional transition-metal carbides: Global screening for new high-capacity battery materials. J Am Chem Soc. 2014; 136 (46): 16270–6.
[36] Naguib M, Come J, Dyatkin B, Presser V, Taberna PL, Simon P, et al. MXene: A promising transition metal carbide anode for lithium-ion batteries. Electrochem commun. 2012; 16 (1): 61–4.
[37] Tang Q, Zhou Z, Shen P. Are MXenes promising anode materials for Li ion batteries? Computational studies on electronic properties and Li storage capability of Ti 3C 2 and Ti 3C 2X 2 (X = F, OH) monolayer. J Am Chem Soc. 2012; 134 (40): 16909–16.
[38] Ortiz-Vitoriano N, Drewett NE, Gonzalo E, Rojo T. High performance manganese-based layered oxide cathodes: Overcoming the challenges of sodium ion batteries. Energy Environ Sci. 2017; 10 (5): 1051–74.
[39] Aslam MK, AlGarni TS, Javed MS, Shah SSA, Hussain S, Xu M. 2D MXene Materials for Sodium Ion Batteries: A review on Energy Storage. J Energy Storage. 2021; 37 (January): 102478.
[40] Slater MD, Kim D, Lee E, Johnson CS. Sodium-ion batteries. Adv Funct Mater. 2013; 23 (8): 947–58.
[41] Vaalma C, Buchholz D, Weil M, Passerini S. A cost and resource analysis of sodium-ion batteries. Nat Rev Mater. 2018; 3.
[42] Yabuuchi N, Kubota K, Dahbi M, Komaba S. Research development on sodium-ion batteries. Chem Rev. 2014; 114 (23): 11636–82.
[43] Kong L, Peng HJ, Huang JQ, Zhang Q. Review of nanostructured current collectors in lithium–sulfur batteries. Nano Res. 2017; 10 (12): 4027–54.
[44] Yin LC, Liang J, Zhou GM, Li F, Saito R, Cheng HM. Understanding the interactions between lithium polysulfides and N-doped graphene using density functional theory calculations. Nano Energy. 2016; 25: 203–10.
[45] Sharon D, Salama M, Attias R, Aurbach D. Electrolyte solutions for “beyond li-ion batteries”: Li-S, Li-O2, and mg batteries. Electrochem Soc Interface. 2019; 28 (2): 71–7.
[46] Liang X, Garsuch A, Nazar LF. Sulfur Cathodes Based on Conductive MXene Nanosheets for High-Performance Lithium-Sulfur Batteries. Angew Chemie. 2015; 127 (13): 3979–83.
[47] Suster D, Michal M, Huang H, Ronen S, Springborn S, Debiec-Rychter M, et al. Myxoinflammatory fibroblastic sarcoma: an immunohistochemical and molecular genetic study of 73 cases. Vol. 33, Modern Pathology. 2020. p. 2520–33.
[48] Liu H, Zhang M, Song Z, Ma T, Huang Z, Wang A, et al. A super hybrid supercapacitor with high energy density based on the construction of CoMoO4/MoO2 decorated 3D sulfur-doped graphene and porous lotus leaves carbon. J Alloys Compd. 2021; 881: 160660.
[49] Zhao S, Dall’Agnese Y, Chu X, Zhao X, Gogotsi Y, Gao Y. Electrochemical Interaction of Sn-Containing MAX Phase (Nb2SnC) with Li-Ions. ACS Energy Lett. 2019; 4: 2452–7.
[50] Hart JL, Hantanasirisakul K, Lang AC, Anasori B, Pinto D, Pivak Y, et al. Control of MXenes’ electronic properties through termination and intercalation. Nat Commun. 2019; 10 (1).
[51] Lukatskaya MR, Mashtalir O, Ren CE, Dall’Agnese Y, Rozier P, Taberna PL, et al. Cation intercalation and high volumetric capacitance of two-dimensional titanium carbide. Science (80-). 2013; 341 (6153): 1502–5.
[52] Hu M, Zhang H, Hu T, Fan B, Wang X, Li Z. Emerging 2D MXenes for supercapacitors: Status, challenges and prospects. Chem Soc Rev. 2020; 49 (18): 6666–93.
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    Adisu Girma Zewudie, Gudisa Hailu Chala. (2022). Recent Advance and Future Perspective of 2D MXene for Energy Storage: Mini Review. Nanoscience and Nanometrology, 8(2), 15-22. https://doi.org/10.11648/j.nsnm.20220802.11

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    Adisu Girma Zewudie; Gudisa Hailu Chala. Recent Advance and Future Perspective of 2D MXene for Energy Storage: Mini Review. Nanosci. Nanometrol. 2022, 8(2), 15-22. doi: 10.11648/j.nsnm.20220802.11

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    Adisu Girma Zewudie, Gudisa Hailu Chala. Recent Advance and Future Perspective of 2D MXene for Energy Storage: Mini Review. Nanosci Nanometrol. 2022;8(2):15-22. doi: 10.11648/j.nsnm.20220802.11

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  • @article{10.11648/j.nsnm.20220802.11,
      author = {Adisu Girma Zewudie and Gudisa Hailu Chala},
      title = {Recent Advance and Future Perspective of 2D MXene for Energy Storage: Mini Review},
      journal = {Nanoscience and Nanometrology},
      volume = {8},
      number = {2},
      pages = {15-22},
      doi = {10.11648/j.nsnm.20220802.11},
      url = {https://doi.org/10.11648/j.nsnm.20220802.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.nsnm.20220802.11},
      abstract = {MXene is deemed to be one of the best attentive materials in an extensive range of applications due to its stupendous optical, electronic, thermal, and mechanical properties. Different MXene-based nanomaterials with extraordinary characteristics have been proposed, prepared, and practiced as a catalyst due to its two-dimensional (2D) structure, large specific surface area, facile decoration, and high adsorption capacity. Transition metal carbides and/or nitrides (MXenes), a developing class of 2D layer-structure compounds, are being given a lot of attention as one of the most promising classes of energy storage materials due to their numerous advantages, including high electrical conductivity, tunable layer structure, small band gap, and functionalized redox active surface. Bottom-up synthesis, which uses chemical vapor deposition, a template approach, and pulsed laser deposition with plasma enhancement, and top-down synthesis, which uses etching and exfoliation, are the two basic types of synthesis. In this review paper, more than 56 articles where reviewed on 2D MXene materials along with their application in energy storage battery. Numerous applications for energy storage exist for nanomaterials based on (2D) MXene. Even though 2D MXene could have some drawbacks, a lot of research has gone into nanoengineering these 2D materials to improve their functionality for real-world applications. Recent literature has described various uses for 2D MXene materials in lithium-ion batteries, sodium-ion batteries, lithium-sulfur batteries, and supercapacitors. To progress in facilitating their industrial application, the difficulty and prospective future are also examined.},
     year = {2022}
    }
    

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    AB  - MXene is deemed to be one of the best attentive materials in an extensive range of applications due to its stupendous optical, electronic, thermal, and mechanical properties. Different MXene-based nanomaterials with extraordinary characteristics have been proposed, prepared, and practiced as a catalyst due to its two-dimensional (2D) structure, large specific surface area, facile decoration, and high adsorption capacity. Transition metal carbides and/or nitrides (MXenes), a developing class of 2D layer-structure compounds, are being given a lot of attention as one of the most promising classes of energy storage materials due to their numerous advantages, including high electrical conductivity, tunable layer structure, small band gap, and functionalized redox active surface. Bottom-up synthesis, which uses chemical vapor deposition, a template approach, and pulsed laser deposition with plasma enhancement, and top-down synthesis, which uses etching and exfoliation, are the two basic types of synthesis. In this review paper, more than 56 articles where reviewed on 2D MXene materials along with their application in energy storage battery. Numerous applications for energy storage exist for nanomaterials based on (2D) MXene. Even though 2D MXene could have some drawbacks, a lot of research has gone into nanoengineering these 2D materials to improve their functionality for real-world applications. Recent literature has described various uses for 2D MXene materials in lithium-ion batteries, sodium-ion batteries, lithium-sulfur batteries, and supercapacitors. To progress in facilitating their industrial application, the difficulty and prospective future are also examined.
    VL  - 8
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Author Information
  • Department of Applied Chemistry, School of Applied Natural Science, Adama Science and Technology University, Adama, Ethiopia

  • Department of Applied Chemistry, School of Applied Natural Science, Adama Science and Technology University, Adama, Ethiopia

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